For already installed package, you must use the following syntax: rpm -ql packagename

 
rpm -ql pciutils
/sbin/lspci
/sbin/setpci
/usr/sbin/update-pciids
/usr/share/doc/pciutils-3.1.10
/usr/share/doc/pciutils-3.1.10/COPYING
/usr/share/doc/pciutils-3.1.10/ChangeLog
/usr/share/doc/pciutils-3.1.10/README
/usr/share/doc/pciutils-3.1.10/pciutils.lsm
/usr/share/man/man8/lspci.8.gz
/usr/share/man/man8/setpci.8.gz
/usr/share/man/man8/update-pciids.8.gz

To list a given uninstalled package, you must use the following syntax: rpm -qlp packagename.rpm

rpm -qlp fping-3.8-1.el6.rf.x86_64.rpm
/usr/sbin/fping
/usr/sbin/fping6
/usr/share/doc/fping-3.8
/usr/share/doc/fping-3.8/COPYING
/usr/share/doc/fping-3.8/ChangeLog
/usr/share/doc/fping-3.8/README
/usr/share/man/man8/fping.8.gz
/usr/share/man/man8/fping6.8.gz